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 Source: Chemical and Biological Terrorism, an overview of the threat. Phillip L. Coule, M.D.
http://www.pemba.utk.edu/bt101/Chem%20and%20Biol%20Terrorism-%20Dr.%20Coule.ppt

In the United States at the time of the French and Indian War, the British provided tainted blankets to Indians with the goal of disabling the opposing forces.
History of Biological Warfare - US